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Cement Composites with Carbon-Based Nanomaterials for 3D Concrete Printing Applications (2023-02)

A Review

10.1002/tcr.202200293

 Basha Shaik,  Rehman Atta,  Aziz Md,  Kim Jung-Hoon
Journal Article - Chemical Record

Abstract

3D concrete printing (3DCP) is an emerging additive manufacturing technology in the construction industry. Its challenges lie in the development of high-performance printable materials and printing processes. Recently developed carbon-based nanomaterials (CBNs) such as graphene, graphene oxide, graphene nanoplatelets, and carbon nanotubes, have various applications due to their exceptional mechanical, chemical, thermal, and electrical characteristics. CBNs also have found potential applications as a concrete ingredient as they enhance the microstructure and modify concrete properties at the molecular level. This paper focuses on state-of-the-art studies on CBNs, 3DCP technology, and CBNs in conventional and 3D printable cement-based composites including CBN dispersion techniques, concrete mixing methods, and fresh and hardened properties of concrete. Furthermore, the current limitations and future perspectives of 3DCP using CBNs to produce high-quality composite mixtures are discussed.

88 References

  1. Aguilar Sanchez Asel, Wangler Timothy, Stefanoni Matteo, Angst Ueli (2022-02)
    Microstructural Examination of Carbonated 3D Printed Concrete
  2. Arunothayan Arun, Nematollahi Behzad, Ranade Ravi, Bong Shin et al. (2020-10)
    Development of 3D Printable Ultra-High-Performance Fiber-Reinforced Concrete for Digital Construction
  3. Asprone Domenico, Menna Costantino, Bos Freek, Salet Theo et al. (2018-06)
    Rethinking Reinforcement for Digital Fabrication with Concrete
  4. Babafemi Adewumi, Kolawole John, Miah Md, Paul Suvash et al. (2021-06)
    A Concise Review on Inter-Layer Bond Strength in 3D Concrete Printing
  5. Bao Yi, Xu Mingfeng, Soltan Daniel, Xia Tian et al. (2018-09)
    Three-Dimensional Printing Multifunctional Engineered Cementitious Composites (ECC) for Structural Elements
  6. Baz Bilal, Aouad Georges, Kleib Joelle, Bulteel David et al. (2021-04)
    Durability-Assessment and Micro-Structural Analysis of 3D Printed Concrete Exposed to Sulfuric-Acid Environments
  7. Bos Freek, Dezaire Steven, Ahmed Zeeshan, Hoekstra Anne et al. (2020-07)
    Bond of Reinforcement-Cable in 3D Printed Concrete
  8. Chen Yu, Figueiredo Stefan, Li Zhenming, Chang Ze et al. (2020-03)
    Improving Printability of Limestone-Calcined-Clay-Based Cementitious Materials by Using Viscosity-Modifying Admixture
  9. Chen Mingxu, Liu Bo, Li Laibo, Cao Lidong et al. (2020-01)
    Rheological Parameters, Thixotropy and Creep of 3D Printed Calcium-Sulfoaluminate-Cement Composites Modified by Bentonite
  10. Cho Seung, Kruger Jacques, Bester Frederick, Heever Marchant et al. (2020-07)
    A Compendious Rheo-Mechanical Test for Printability-Assessment of 3D Printable Concrete
  11. Dedenis Marie, Sonebi Mohammed, Amziane Sofiane, Perrot Arnaud et al. (2020-07)
    Effect of Metakaolin, Fly-Ash and Polypropylene-Fibers on Fresh and Rheological Properties of 3D Printing Based Cement Materials
  12. Ducoulombier Nicolas, Carneau Paul, Mesnil Romain, Demont Léo et al. (2020-07)
    The Slug-Test:
    In-Line-Assessment of Yield-Stress for Extrusion-Based Additive Manufacturing
  13. Ducoulombier Nicolas, Mesnil Romain, Carneau Paul, Demont Léo et al. (2021-05)
    The “Slugs-Test” for Extrusion-Based Additive Manufacturing:
    Protocol, Analysis and Practical Limits
  14. Dulaj Albanela, Suijs Monica, Salet Theo, Lucas Sandra (2022-06)
    Incorporation and Characterization of Multi-Walled Carbon Nanotube Concrete Composites for 3D Printing Applications
  15. Gaudillière-Jami Nadja, Duballet Romain, Bouyssou Charles, Mallet Alban et al. (2018-09)
    Large-Scale Additive Manufacturing of Ultra-High-Performance Concrete of Integrated Formwork for Truss-Shaped Pillars
  16. Gosselin Clément, Duballet Romain, Roux Philippe, Gaudillière-Jami Nadja et al. (2016-03)
    Large-Scale 3D Printing of Ultra-High-Performance Concrete:
    A New Processing Route for Architects and Builders
  17. Hass Lauri, Bos Freek (2020-07)
    Bending and Pull-Out Tests on a Novel Screw Type Reinforcement for Extrusion-Based 3D Printed Concrete
  18. He Lewei, Li Hua, Chow Wai, Zeng Biqing et al. (2022-09)
    Increasing the Inter-Layer Strength of 3D Printed Concrete with Tooth-Like Interface:
    An Experimental and Theoretical Investigation
  19. Heever Marchant, Bester Frederick, Kruger Jacques, Zijl Gideon (2021-07)
    Mechanical Characterisation for Numerical Simulation of Extrusion-Based 3D Concrete Printing
  20. Jayathilakage Roshan, Sanjayan Jay, Rajeev Pathmanathan (2019-01)
    Direct-Shear-Test for the Assessment of Rheological Parameters of Concrete for 3D Printing Applications
  21. Joh Changbin, Lee Jungwoo, Bui The, Park Jihun et al. (2020-11)
    Buildability and Mechanical Properties of 3D Printed Concrete
  22. Kazemian Ali, Yuan Xiao, Cochran Evan, Khoshnevis Behrokh (2017-04)
    Cementitious Materials for Construction-Scale 3D Printing:
    Laboratory Testing of Fresh Printing Mixture
  23. Khalil Noura, Aouad Georges, Cheikh Khadija, Rémond Sébastien (2017-09)
    Use of Calcium-Sulfoaluminate-Cements for Setting-Control of 3D Printing Mortars
  24. Kilic Ugur, Jiang Zhangfan, Ma Ji, Ozbulut Osman (2021-03)
    Printability Characterization of Graphene-Reinforced Cementitious Composites
  25. Kinomura Koji, Murata Satoshi, Yamamoto Yujin, Obi Hirotoshi et al. (2020-07)
    Application of 3D Printed Segments Designed by Topology-Optimization-Analysis to a Practical-Scale Pre-Stressed Pedestrian Bridge
  26. Kosson Michael, Brown Lesa, Sanchez Florence (2020-01)
    Early-Age Performance of 3D Printed Carbon-Nano-Fiber and Carbon Micro-Fiber Cement Composites
  27. Kruger Jacques, Cho Seung, Zeranka Stephan, Vintila Cristian et al. (2019-12)
    3D Concrete Printer Parameter Optimization for High-Rate Digital Construction Avoiding Plastic Collapse
  28. Kruger Jacques, Zeranka Stephan, Zijl Gideon (2019-07)
    An Ab-Inito Approach for Thixotropy Characterisation of Nano-Particle-Infused 3D Printable Concrete
  29. Le Thanh, Austin Simon, Lim Sungwoo, Buswell Richard et al. (2012-01)
    Mix-Design and Fresh Properties for High-Performance Printing Concrete
  30. Lee Jin, Kim Jae (2022-05)
    Matric-Suction of Fine Sand and Its Effect on the Shape Stability of 3D Printed Cement Mortar
  31. Lee Hojae, Kim Jang-Ho, Moon Jae-Heum, Kim Won-Woo et al. (2019-12)
    Evaluation of the Mechanical Properties of a 3D Printed Mortar
  32. Liu Junli, Li Shuai, Gunasekara Chamila, Fox Kate et al. (2021-11)
    3D Printed Concrete with Recycled Glass:
    Effect of Glass Gradation on Flexural Strength and Microstructure
  33. Marchment Taylor, Sanjayan Jay, Xia Ming (2019-03)
    Method of Enhancing Inter-Layer Bond Strength in Construction-Scale 3D Printing with Mortar by Effective Bond Area Amplification
  34. Markin Slava, Ivanova Irina, Fataei Shirin, Reißig Silvia et al. (2020-07)
    Investigation on Structural Build-Up of 3D Printable Foam-Concrete
  35. Mazhoud Brahim, Perrot Arnaud, Picandet Vincent, Rangeard Damien et al. (2019-04)
    Underwater 3D Printing of Cement-Based Mortar
  36. Mechtcherine Viktor, Nerella Venkatesh, Will Frank, Näther Mathias et al. (2019-08)
    Large-Scale Digital Concrete Construction:
    CONPrint3D Concept for On-Site, Monolithic 3D Printing
  37. Moelich Gerrit, Kruger Jacques, Combrinck Riaan (2020-08)
    Plastic Shrinkage Cracking in 3D Printed Concrete
  38. Mohammed Alyaa, Saadi Nihad (2020-12)
    Ultra-High Early Strength Cementitious Grout Suitable for Additive Manufacturing Applications Fabricated by Using Graphene Oxide and Viscosity Modifying Agents
  39. Moini Mohamadreza, Baghaie Ahmadreza, Rodriguez Fabian, Zavattieri Pablo et al. (2021-06)
    Quantitative Microstructural Investigation of 3D Printed and Cast Cement-Pastes Using Micro-Computed Tomography- and Image-Analysis
  40. Nair Sooraj, Panda Subhashree, Santhanam Manu, Sant Gaurav et al. (2020-05)
    A Critical Examination of the Influence of Material-Characteristics and Extruder-Geometry on 3D Printing of Cementitious Binders
  41. Nerella Venkatesh, Hempel Simone, Mechtcherine Viktor (2019-02)
    Effects of Layer-Interface Properties on Mechanical Performance of Concrete Elements Produced by Extrusion-Based 3D Printing
  42. Nerella Venkatesh, Näther Mathias, Iqbal Arsalan, Butler Marko et al. (2018-09)
    In-Line Quantification of Extrudability of Cementitious Materials for Digital Construction
  43. Ogura Hiroki, Nerella Venkatesh, Mechtcherine Viktor (2018-08)
    Developing and Testing of Strain-Hardening Cement-Based Composites (SHCC) in the Context of 3D Printing
  44. Pan Tinghong, Guo Rongxin, Jiang Yaqing, Ji Xuping et al. (2022-11)
    Flow and Deformation Behaviors of Cementitious Materials Through Nozzles with Different Geometric Parameters:
    Experimental and Numerical Approaches
  45. Panda Biranchi, Mohamed Nisar, Paul Suvash, Bhagath Singh Gangapatnam et al. (2019-07)
    The Effect of Material Fresh Properties and Process Parameters on Buildability and Inter-Layer Adhesion of 3D Printed Concrete
  46. Panda Biranchi, Tan Ming (2018-03)
    Experimental Study on Mix Proportion and Fresh Properties of Fly-Ash-Based Geopolymer for 3D Concrete Printing
  47. Panda Biranchi, Unluer Cise, Tan Ming (2018-10)
    Investigation of the Rheology and Strength of Geopolymer Mixtures for Extrusion-Based 3D Printing
  48. Perrot Arnaud, Rangeard Damien, Pierre Alexandre (2015-02)
    Structural Build-Up of Cement-Based Materials Used for 3D Printing-Extrusion-Techniques
  49. Putten Jolien, Schutter Geert, Tittelboom Kim (2018-09)
    The Effect of Print Parameters on the (Micro)structure of 3D Printed Cementitious Materials
  50. Putten Jolien, Volder Melissa, Heede Philip, Schutter Geert et al. (2020-07)
    3D Printing of Concrete:
    The Influence on Chloride Penetration
  51. Rahul Attupurathu, Santhanam Manu (2020-02)
    Evaluating the Printability of Concretes Containing Lightweight Coarse Aggregates
  52. Rahul Attupurathu, Santhanam Manu, Meena Hitesh, Ghani Zimam (2018-12)
    3D Printable Concrete:
    Mixture-Design and Test-Methods
  53. Rahul Attupurathu, Santhanam Manu, Meena Hitesh, Ghani Zimam (2019-08)
    Mechanical Characterization of 3D Printable Concrete
  54. Rehman Atta, Kim Jung-Hoon (2021-07)
    3D Concrete Printing:
    A Systematic Review of Rheology, Mix Designs, Mechanical, Microstructural, and Durability Characteristics
  55. Rehman Atta, Lee Sang-Min, Kim Jung-Hoon (2020-06)
    Use of Municipal Solid-Waste Incineration-Ash in 3D Printable Concrete
  56. Reiter Lex, Wangler Timothy, Anton Ana-Maria, Flatt Robert (2020-05)
    Setting-on-Demand for Digital Concrete:
    Principles, Measurements, Chemistry, Validation
  57. Reiter Lex, Wangler Timothy, Roussel Nicolas, Flatt Robert (2022-04)
    Slow Penetration for Characterizing Concrete for Digital Fabrication
  58. Rubin Ariane, Hasse Jéssica, Repette Wellington (2021-01)
    The Evaluation of Rheological Parameters of 3D Printable Concretes and the Effect of Accelerating-Admixture
  59. Sambucci Matteo, Valente Marco, Sibai Abbas, Marini Danilo et al. (2020-07)
    Rubber-Cement Composites for Additive Manufacturing:
    Physical, Mechanical and Thermo-Acoustic Characterization
  60. Sanjayan Jay, Nematollahi Behzad, Xia Ming, Marchment Taylor (2018-04)
    Effect of Surface Moisture on Inter-Layer Strength of 3D Printed Concrete
  61. Sanjayan Jay, Nematollahi Behzad, Xia Ming, Marchment Taylor (2021-06)
    Effect of Surface Moisture on Inter-Layer Strength of 3D Printed Concrete:
    Correction
  62. Schröfl Christof, Nerella Venkatesh, Mechtcherine Viktor (2018-09)
    Capillary Water Intake by 3D Printed Concrete Visualised and Quantified by Neutron Radiography
  63. Sergis Vasileios, Ouellet-Plamondon Claudiane (2022-07)
    Automating Mix-Design for 3D Concrete Printing Using Optimization Methods
  64. Sikora Paweł, Chung Sang-Yeop, Liard Maxime, Lootens Didier et al. (2021-02)
    The Effects of Nano-Silica on the Fresh and Hardened Properties of 3D Printable Mortars
  65. Sikora Paweł, Techman Mateusz, Federowicz Karol, Khayatt Ahmed et al. (2022-07)
    Insight into the Microstructural and Durability Characteristics of 3D Printed Concrete:
    Cast versus Printed Specimens
  66. Sun Xiaoyan, Wang Qun, Wang Hailong, Chen Long (2020-03)
    Influence of Multi-Walled Nanotubes on the Fresh and Hardened Properties of a 3D Printing PVA Mortar Ink
  67. Suntharalingam Thadshajini, Nagaratnam Brabha, Poologanathan Keerthan, Hackney Phil et al. (2020-07)
    Effect of Polypropylene-Fibers on the Mechanical Properties of Extrudable Cementitious Material
  68. Suntharalingam Thadshajini, Upasiri Irindu, Gatheeshgar Perampalam, Poologanathan Keerthan et al. (2021-09)
    Energy Performance of 3D Printed Concrete Walls:
    A Numerical Study
  69. Tao Yaxin, Lesage Karel, Tittelboom Kim, Yuan Yong et al. (2020-07)
    Effect of Limestone-Powder Substitution on Fresh and Hardened Properties of 3D Printable Mortar
  70. Vaitkevičius Vitoldas, Šerelis Evaldas, Kerševičius Vidas (2018-03)
    Effect of Ultra-Sonic Activation on Early Hydration Process in 3D Concrete Printing Technology
  71. Wang Lining, Aslani Farhad, Mukherjee Abhijit (2022-04)
    Development of 3D Printable Self-Sensing Cementitious Composites
  72. Wang Xianggang, Jia Lutao, Jia Zijian, Zhang Chao et al. (2022-06)
    Optimization of 3D Printing Concrete with Coarse Aggregate via Proper Mix-Design and Printing-Process
  73. Wang Weiqiang, Konstantinidis Nikolaos, Austin Simon, Buswell Richard et al. (2020-07)
    Flexural Behavior of AR-Glass-Textile-Reinforced 3D Printed Concrete Beams
  74. Wangler Timothy, Lloret-Fritschi Ena, Reiter Lex, Hack Norman et al. (2016-10)
    Digital Concrete:
    Opportunities and Challenges
  75. Wangler Timothy, Pileggi Rafael, Gürel Şeyma, Flatt Robert (2022-03)
    A Chemical Process Engineering Look at Digital Concrete Processes:
    Critical Step Design, In-Line Mixing, and Scale-Up
  76. Wang Li, Xiao Wei, Wang Qiao, Jiang Hailong et al. (2022-07)
    Freeze-Thaw-Resistance of 3D Printed Composites with Desert Sand
  77. Wolfs Robert, Bos Freek, Salet Theo (2018-06)
    Correlation Between Destructive Compression Tests and Non-Destructive Ultrasonic Measurements on Early-Age 3D Printed Concrete
  78. Wolfs Robert, Bos Freek, Salet Theo (2018-02)
    Early-Age Mechanical Behaviour of 3D Printed Concrete:
    Numerical Modelling and Experimental Testing
  79. Wolfs Robert, Bos Freek, Salet Theo (2019-03)
    Hardened Properties of 3D Printed Concrete:
    The Influence of Process Parameters on Inter-Layer Adhesion
  80. Wolfs Robert, Bos Freek, Salet Theo (2019-06)
    Triaxial Compression Testing on Early-Age Concrete for Numerical Analysis of 3D Concrete Printing
  81. Wu Yun-Chen, Li Mo (2022-09)
    Effects of Early-Age Rheology and Printing Time Interval on Late-Age Fracture Characteristics of 3D Printed Concrete
  82. Xu Yading, Schlangen Erik, Šavija Branko (2020-07)
    Auxetic Behavior of Cementitious Cellular Composites under Uniaxial Compression and Cyclic Loading
  83. Zhang Chao, Nerella Venkatesh, Krishna Anurag, Wang Shen et al. (2021-06)
    Mix-Design Concepts for 3D Printable Concrete:
    A Review
  84. Zhang Hanghua, Xiao Jianzhuang, Duan Zhenhua, Zou Shuai et al. (2022-06)
    Effects of Printing Paths and Recycled Fines on Drying Shrinkage of 3D Printed Mortar
  85. Zhang Yu, Zhang Yunsheng, Liu Guojian, Yang Yonggan et al. (2018-04)
    Fresh Properties of a Novel 3D Printing Concrete Ink
  86. Zhang Yu, Zhang Yunsheng, She Wei, Yang Lin et al. (2019-01)
    Rheological and Hardened Properties of the High-Thixotropy 3D Printing Concrete
  87. Zhang Yu, Zhang Yunsheng, Yang Lin, Liu Guojian et al. (2021-02)
    Hardened Properties and Durability of Large-Scale 3D Printed Cement-Based Materials
  88. Zou Shuai, Xiao Jianzhuang, Duan Zhenhua, Ding Tao et al. (2021-10)
    On Rheology of Mortar with Recycled Fine Aggregate for 3D Printing

15 Citations

  1. Iqbal Imtiaz, Kasim Tala, Besklubova Svetlana, Inqiad Waleed et al. (2025-12)
    Exploring Knowledge Domains and Future Research Directions in 3D Printed Concrete:
    A Bibliometric and Systematic Review
  2. Jiang Youbau, Wen Jun, Gao Pengxiang, Liu Yan et al. (2025-09)
    Effect of Graphene Oxide on Physical and Mechanical Properties of 3D Printed Concrete
  3. Bajwa Asad, Flemmer Claire, Samarasinghe Don, Bao Ding et al. (2025-07)
    Sustainability of 3D Printing Technology:
    A Review on Research Trends and Developments
  4. Surehali Sahil, Venkatachalam Akshay, Divigalpitiya Ranjith, Kumar Aditya et al. (2025-06)
    Ultra-Low Dosages of Novel Graphene Types Enhance the Rheological Properties and Buildability of 3D Printed Binders
  5. Irshidat Mohammad, Cabibihan John-John, Fadli Fodil, Ramahi Siraj et al. (2024-12)
    Waste Materials Utilization in 3D Printable Concrete for Sustainable Construction Applications:
    A Review
  6. Lucas Sandra (2024-11)
    From 3D to 5D Printing:
    Additive Manufacturing of Functional Construction Materials
  7. Sousa Israel, Alessandro Antonella, Mesquita Esequiel, Laflamme Simon et al. (2024-11)
    Comprehensive Review of 3D Printed Cementitious Composites with Carbon Inclusions:
    Current Status and Perspective for Self-Sensing Capabilities
  8. Jin Peng, Hasany Masoud, Kohestanian Mohammad, Mehrali Mehdi (2024-10)
    Micro/Nano Additives in 3D Printing Concrete:
    Opportunities, Challenges, and Potential Outlook in Construction Applications
  9. Baytak Tugba, Gdeh Tawfeeq, Jiang Zhangfan, Arce Gabriel et al. (2024-09)
    Rheological, Mechanical, and Environmental Performance of Printable Graphene-Enhanced Cementitious Composites with Limestone and Calcined Clay
  10. Rehman Atta, Basha Shaik, Choi Kichang, Kang Manmin et al. (2024-07)
    An Analysis of Penetrometer-Test Methods for Structural Build-Up in Stiff and Accelerated 3D Concrete Printing Mixtures
  11. Basha Shaik, Nugraha Joshua, Rehman Atta, Choi Kichang et al. (2024-06)
    Structuration and Yield Strength Characterization of Hybrid Alkali-Activated Cement Composites for Ultra-Rapid 3D Construction Printing
  12. Birru Bizu, Rehman Atta, Kim Jung-Hoon (2024-06)
    Comparative Analysis of Structural Build-Up in One-Component Stiff and Two-Component Shotcrete-Accelerated Set-on-Demand Mixtures for 3D Concrete Printing
  13. Rehman Atta, Kim Ik-Gyeom, Kim Jung-Hoon (2024-01)
    Towards Full Automation in 3D Concrete Printing Construction:
    Development of an Automated and In-Line Test-Method for In-Situ Assessment of Structural Build-Up and Quality of Concrete
  14. Sahai Rajan, Bisht Ravindra, Malviya Nitesh, Kumar Shivam et al. (2024-01)
    Aspects of Waste-Material-Utilization and 3D Concrete Printer Development-Approach:
    A Review
  15. Rehman Atta, Perrot Arnaud, Birru Bizu, Kim Jung-Hoon (2023-09)
    Recommendations for Quality-Control in Industrial 3D Concrete Printing Construction with Mono-Component Concrete:
    A Critical Evaluation of Ten Test-Methods and the Introduction of the Performance-Index

BibTeX
@article{bash_rehm_aziz_kim.2023.CCwCBNf3CPA,
  author            = "Shaik Inayath Basha and Atta Ur Rehman and Md Abdul Aziz and Jung-Hoon Kim",
  title             = "Cement Composites with Carbon-Based Nanomaterials for 3D Concrete Printing Applications: A Review",
  doi               = "10.1002/tcr.202200293",
  year              = "2023",
  journal           = "Chemical Record",
}
Formatted Citation

S. I. Basha, A. U. Rehman, M. A. Aziz and J.-H. Kim, “Cement Composites with Carbon-Based Nanomaterials for 3D Concrete Printing Applications: A Review”, Chemical Record, 2023, doi: 10.1002/tcr.202200293.

Basha, Shaik Inayath, Atta Ur Rehman, Md Abdul Aziz, and Jung-Hoon Kim. “Cement Composites with Carbon-Based Nanomaterials for 3D Concrete Printing Applications: A Review”. Chemical Record, 2023. https://doi.org/10.1002/tcr.202200293.