Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete (2025-05)¶
, ,
Journal Article - Materials Today Sustainability, No. 101131
Abstract
3D printing of geopolymer is considered an alternative to cement-based concrete due to its sustainability and novel manufacturing techniques. Comparisons have been drawn between one-part and two-part 3D-printed geopolymer concrete (OP3DPGPC and TP3DPGPC, respectively). Some articles have projected OP3DPGPC to be user-friendly since it is excited with powdered activators. However, the embodied energy and the carbon emission of liquid silicate reactants in TP3DPGPC are 70% and 50% less than the solid silicate used in OP3DPGPC. Also, studies show that TP3DPGPC exhibits superior mechanical performance compared to OP3DPGPC. This study comprehensively reviews the advances in the laboratory-scale and real-scale development of extrusion-based TP3DPGPC, their material composition, constituents’ proportion, and mechanical performance. Data were collected from articles published on TP3DPGPC across renowned journals from 2017 to 2024 and internet sources to identify real-scale TP3DPGPC structures. The mechanical properties of TP3DPGPC available in the literature include compression, flexure, interlayer bond, tensile bond, direct tensile, and splitting tensile strength. These studies show that the mechanical performance of TP3DPGPC depends on the type and proportion of precursor(s), type and composition of the reactants, aggregate type, aggregate-to-binder ratio, activator-to-binder ratio, the molarity of NaOH, SiO2/Na2O ratio, water-to-binder ratio, water-to-solid ratio, liquid-to-solid ratio, additive types, fibre (type, content, and aspect ratio), and curing (type and conditions). Similarly, the mechanical performance of TP3DPGPC is dependent on the printer parameters, the configuration, and the loading direction. The data generated will serve as the basis for future studies and the prediction of mechanical performance. Finally, a review of the microstructure properties is conducted to justify the mechanical performance.
¶
75 References
- Alghamdi Hussam, Nair Sooraj, Neithalath Narayanan (2019-02)
Insights into Material-Design, Extrusion Rheology, and Properties of 3D Printable Alkali-Activated Fly-Ash-Based Binders - Alghamdi Hussam, Neithalath Narayanan (2019-07)
Synthesis and Characterization of 3D Printable Geopolymeric Foams for Thermally Efficient Building Envelope Materials - Al-Qutaifi Sarah, Nazari Ali, Bagheri Ali (2018-07)
Mechanical Properties of Layered Geopolymer Structures Applicable in Concrete 3D Printing - Bester Frederick, Heever Marchant, Kruger Jacques, Zijl Gideon (2020-11)
Reinforcing Digitally Fabricated Concrete:
A Systems Approach Review - Bhattacherjee Shantanu, Basavaraj Anusha, Rahul Attupurathu, Santhanam Manu et al. (2021-06)
Sustainable Materials for 3D Concrete Printing - Bong Shin, Nematollahi Behzad, Xia Ming, Ghaffar Seyed et al. (2022-04)
Properties of Additively Manufactured Geopolymer Incorporating Mineral-Wollastonite-Micro-Fibers - Bong Shin, Xia Ming, Nematollahi Behzad, Shi Caijun (2021-04)
Ambient Temperature Cured ‘Just-Add-Water’ Geopolymer for 3D Concrete Printing Applications - Chaiyotha Danai, Kantawong Watcharapong, Payakanitia Panjasila, Pinitsoontorn Supree et al. (2023-03)
Finding Optimized Conditions for 3D Printed High-Calcium Fly-Ash-Based Alkali-Activated Mortar - Chen Kailun, Liu Qiong, Chen Bing, Zhang Shishun et al. (2024-01)
A Review on Effect of Raw Materials on the Performance of 3D Printed Geopolymer System for Construction - Chen Yuning, Xia Kailun, Jia Zijian, Gao Yueyi et al. (2023-10)
Extending Applicability of 3D Printable Geopolymer to Large-Scale Printing Scenario via Combination of Sodium Carbonate and Nano-Silica - Chen Zhengyuan, Yang Shutong, Liu Qi, Xu Mingqi et al. (2024-03)
Closed-Form Fracture-Model for Evaluating Crack-Resistance of 3D Printed Fiber-Reinforced Alkali-Activated Slag/Fly-Ash Recycled-Sand Concrete - Chen Yuxuan, Zhang Longfei, Wei Kai, Gao Huaxing et al. (2024-04)
Rheology-Control and Shrinkage-Mitigation of 3D Printed Geopolymer Concrete Using Nano-Cellulose and Magnesium-Oxide - Chen Yuning, Zhang Yamei, Xie Yudong, Zhang Zedi et al. (2022-09)
Unraveling Pore-Structure Alternations in 3D Printed Geopolymer Concrete and Corresponding Impacts on Macro-Properties - Chougan Mehdi, Ghaffar Seyed, Jahanzat Mohammad, Albar Abdulrahman et al. (2020-04)
The Influence of Nano-Additives in Strengthening Mechanical Performance of 3D Printed Multi-Binder Geopolymer Composites - Chougan Mehdi, Ghaffar Seyed, Sikora Paweł, Chung Sang-Yeop et al. (2021-02)
Investigation of Additive Incorporation on Rheological, Microstructural and Mechanical Properties of 3D Printable Alkali-Activated Materials - Christ Julian, Perrot Arnaud, Ottosen Lisbeth, Koss Holger (2023-12)
Rheological Characterization of Temperature-Sensitive Biopolymer-Bound 3D Printing Concrete - Colyn Markus, Zijl Gideon, Babafemi Adewumi (2024-02)
Fresh and Strength Properties of 3D Printable Concrete Mixtures Utilising a High Volume of Sustainable Alternative Binders - Demiral Nazim, Ozkan Ekinci Mehmet, Şahin Oğuzhan, İlcan Hüseyin et al. (2022-10)
Mechanical Anisotropy Evaluation and Bonding Properties of 3D Printable Construction and Demolition Waste-Based Geopolymer Mortars - Guo Xiaolu, Yang Junyi, Xiong Guiyan (2020-09)
Influence of Supplementary Cementitious Materials on Rheological Properties of 3D Printed Fly-Ash-Based Geopolymer - Heever Marchant, Bester Frederick, Kruger Jacques, Zijl Gideon (2021-07)
Mechanical Characterisation for Numerical Simulation of Extrusion-Based 3D Concrete Printing - Ibrahim Kamoru, Zijl Gideon, Babafemi Adewumi (2024-04)
Mitigation of Lack-of-Fusion in 3D Printed Limestone-Calcined-Clay-Cement Concrete Induced by Effective Micro-Organisms - İlcan Hüseyin, Külak Adnan, Şahmaran Mustafa (2024-03)
3D Printable Construction and Demolition Waste-Based Geopolymer:
Investigating the Effects of Additives on Engineering Properties - İlcan Hüseyin, Şahin Oğuzhan, Kul Anil, Yıldırım Gürkan et al. (2022-03)
Rheological Properties and Compressive Strength of Construction and Demolition Waste-Based Geopolymer Mortars for 3D Printing - Imram Ramsha, Rashid Ans, Khan Shoukat, İlcan Hüseyin et al. (2023-10)
Buildability-Analysis on Squared Profile Structure in 3D Concrete Printing - Jaji Mustapha, Ibrahim Kamoru, Zijl Gideon, Babafemi Adewumi (2023-04)
Thixotropic Characterisation of Slag-Modified 3D Printable Metakaolin-Based Geopolymer Composite - Jaji Mustapha, Kamoru A., Zijl Gideon, Babafemi Adewumi (2023-07)
Effect of Anisotropy on Permeability Index and Water-Absorption of 3D Printed Metakaolin-Based Geopolymer Concrete - Jaji Mustapha, Zijl Gideon, Babafemi Adewumi (2022-09)
Fresh Properties and Strength Evolution of Slag-Modified Fiber-Reinforced Metakaolin-Based Geopolymer Composite for 3D Concrete Printing Application - Jaji Mustapha, Zijl Gideon, Babafemi Adewumi (2023-08)
Slag-Modified Fiber-Reinforced Metakaolin-Based Geopolymer for 3D Concrete Printing Application:
Evaluating Fresh and Hardened Properties - Jaji Mustapha, Zijl Gideon, Babafemi Adewumi (2023-11)
Slag-Modified Metakaolin-Based 3D Printed Geopolymer:
Mechanical Characterisation, Microstructural Properties, and Nitrogen Physisorption Pore-Analysis - Jaji Mustapha, Zijl Gideon, Babafemi Adewumi (2024-03)
Durability and Pore-Structure of Metakaolin-Based 3D Printed Geopolymer Concrete - Khan Shoukat, İlcan Hüseyin, Aminipour Ehsan, Şahin Oğuzhan et al. (2023-07)
Buildability-Analysis on Effect of Structural Design in 3D Concrete Printing:
An Experimental and Numerical Study - Khan Shoukat, İlcan Hüseyin, Imram Ramsha, Aminipour Ehsan et al. (2024-01)
The Impact of Nozzle-Diameter and Printing Speed on Geopolymer-Based 3D Printed Concrete Structures:
Numerical Modeling and Experimental Validation - Le Thanh, Austin Simon, Lim Sungwoo, Buswell Richard et al. (2012-01)
Hardened Properties of High-Performance Printing Concrete - Li Zhijian, Wang Li, Ma Guowei (2020-01)
Mechanical Improvement of Continuous Steel-Micro-Cable-Reinforced Geopolymer Composites for 3D Printing Subjected to Different Loading Conditions - Lim Jian, Panda Biranchi, Pham Quang-Cuong (2018-05)
Improving Flexural Characteristics of 3D Printed Geopolymer Composites with In-Process Steel-Cable-Reinforcement - Liu Xinhao, Hu Jiajun, Guo Xiaolu (2024-03)
Printability and Inter-Layer Bonding Property of 3D Printed Fiber-Reinforced Geopolymer - Ma Guowei, Li Zhijian, Wang Li, Bai Gang (2018-10)
Micro-Cable-Reinforced Geopolymer Composite for Extrusion-Based 3D Printing - Ma Guowei, Yan Yufei, Zhang Mo, Sanjayan Jay (2022-05)
Effect of Steel-Slag on 3D Concrete Printing of Geopolymer with Quaternary Binders - Marczyk Joanna, Ziejewska Celina, Korniejenko Kinga, Łach Michał et al. (2022-09)
Properties of 3D Printed Concrete-Geopolymer Hybrids Reinforced with Aramid Roving - Moelich Gerrit, Kruger Jacques, Combrinck Riaan (2021-09)
Modelling the Inter-Layer Bond Strength of 3D Printed Concrete with Surface Moisture - Moraes Maria, Nagata Ester, Duran Afonso, Rossignolo João (2024-02)
Alkali-Activated Materials Applied in 3D Printing Construction:
A Review - Mujeeb Syed, Samudrala Manideep, Lanjewar Bhagyashri, Chippagiri Ravijanya et al. (2023-05)
Development of Alkali-Activated 3D Printable Concrete:
A Review - Munemo Rue, Kruger Jacques, Zijl Gideon (2023-06)
Improving Inter-Layer Bond in 3D Printed Concrete Through Induced Thermo-Hydrokinetics - Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2020-09)
Effect of Microwave-Heating on Inter-Layer Bonding and Buildability of Geopolymer 3D Concrete Printing - Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2021-06)
Technologies for Improving Buildability in 3D Concrete Printing - Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2022-10)
In-Line Activation of Geopolymer-Slurry for Concrete 3D Printing - Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2022-02)
Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing - Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2023-09)
Rapid Early-Age Strength Development of In-Line Activated Geopolymer for Concrete 3D Printing - Noaimat Yazeed, Ghaffar Seyed, Chougan Mehdi, Kheetan Mazen (2022-12)
A Review of 3D Printing Low-Carbon Concrete with One-Part Geopolymer:
Engineering, Environmental and Economic Feasibility - Panda Biranchi, Bhagath Singh Gangapatnam, Unluer Cise, Tan Ming (2019-02)
Synthesis and Characterization of One-Part Geopolymers for Extrusion-Based 3D Concrete Printing - Panda Biranchi, Paul Suvash, Lim Jian, Tay Yi et al. (2017-08)
Additive Manufacturing of Geopolymer for Sustainable Built Environment - Panda Biranchi, Paul Suvash, Mohamed Nisar, Tay Yi et al. (2017-09)
Measurement of Tensile Bond Strength of 3D Printed Geopolymer Mortar - Panda Biranchi, Paul Suvash, Tan Ming (2017-07)
Anisotropic Mechanical Performance of 3D Printed Fiber-Reinforced Sustainable Construction-Material - Panda Biranchi, Ruan Shaoqin, Unluer Cise, Tan Ming (2020-01)
Investigation of the Properties of Alkali-Activated Slag Mixes Involving the Use of Nano-Clay and Nucleation-Seeds for 3D Printing - Panda Biranchi, Tan Ming (2018-03)
Experimental Study on Mix Proportion and Fresh Properties of Fly-Ash-Based Geopolymer for 3D Concrete Printing - Panda Biranchi, Tan Ming (2018-11)
Rheological Behavior of High-Volume Fly-Ash Mixtures Containing Micro-Silica for Digital Construction Application - Panda Biranchi, Unluer Cise, Tan Ming (2018-10)
Investigation of the Rheology and Strength of Geopolymer Mixtures for Extrusion-Based 3D Printing - Panda Biranchi, Unluer Cise, Tan Ming (2019-08)
Extrusion and Rheology Characterization of Geopolymer Nanocomposites Used in 3D Printing - Paritala Spandana, Singaram Kailash, Bathina Indira, Khan Mohd et al. (2023-08)
Rheology and Pumpability of Mix Suitable for Extrusion-Based Concrete 3D Printing:
A Review - Pasupathy Kirubajiny, Ramakrishnan Sayanthan, Sanjayan Jay (2023-01)
3D Concrete Printing of Eco-Friendly Geopolymer Containing Brick Waste - Paul Suvash, Basit Md, Hasan Noor, Dey Dhrutiman et al. (2023-04)
3D Printing of Geopolymer Mortar:
Overview of the Effect of Mix-Design and Printing Parameters on the Strength - Perales-Santillan M., Díaz-Aguilera Jorge, Mendoza-Rangel Jose (2024-02)
Evaluation of the Rheological Behavior for Alkaline-Activated Cements of Metakaolin and Limestone for Its Potential Application in 3D Printing - Qaidi Shaker, Yahia Ammar, Tayeh B., Unis H. et al. (2022-10)
3D Printed Geopolymer Composites:
A Review - Rahemipoor Sahand, Hasany Masoud, Mehrali Mohammad, Almdal Kristoffer et al. (2023-07)
Phase-Change-Materials Incorporation into 3D Printed Geopolymer Cement:
A Sustainable Approach to Enhance the Comfort and Energy Efficiency of Buildings - Ramezani Amir, Modaresi Shahriar, Dashti Pooria, Givkashi Mohammad et al. (2023-04)
Effects of Different Types of Fibers on Fresh and Hardened Properties of Cement and Geopolymer-Based 3D Printed Mixtures:
A Review - Raza Muhammad, Zhong Ray (2022-08)
A Sustainable Roadmap for Additive Manufacturing Using Geopolymers in Construction Industry - Roux Charlotte, Archez Julien, Gall Corentin, Saadé Myriam et al. (2024-04)
Towards Sustainable Material:
Optimizing Geopolymer Mortar Formulations for 3D Printing - Saadati Farzaneh, Kani Ebrahim (2023-09)
Phosphorous Slag-Based Geopolymer Cement Incorporate with Mullite for 3D Printing Application - Sayegh Sameh, Romdhane Lotfi, Manjikian Solair (2022-03)
A Critical Review of 3D Printing in Construction:
Benefits, Challenges, and Risks - Shahmirzadi Mohsen, Gholampour Aliakbar, Kashani Alireza, Ngo Tuan (2023-10)
Geopolymer Mortars for Use in Construction 3D Printing:
Effect of LSS, Graphene-Oxide and Nano-Clay at Different Environmental Conditions - Shilar Fatheali, Ganachari Sharanabasava, Patil Veerabhadragouda, Bhojaraja B. et al. (2023-08)
A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications - Yoris-Nobile Adrian, Lizasoain-Arteaga Esther, Slebi-Acevedo Carlos, Blanco-Fernandez Elena et al. (2022-07)
Life-Cycle-Assessment and Multi-Criteria Decision-Making-Analysis to Determine the Performance of 3D Printed Cement Mortars and Geopolymers - Zhong Hui, Zhang Mingzhong (2022-02)
3D Printing Geopolymers:
A Review - Ziada Mahmoud, Tanyildizi Harun, Seloglu Maksut, Coskun Ahmet (2024-02)
Bacteria-Based Crack-Healing of 3D Printed PVA-Fiber-Reinforced Geopolymer Mortars - Ziejewska Celina, Marczyk Joanna, Korniejenko Kinga, Bednarz Sebastian et al. (2022-04)
3D Printing of Concrete-Geopolymer Hybrids
0 Citations
BibTeX
@article{jaji_baba_zijl.2025.MPoEBTP3PGC,
author = "Mustapha Bamidele Jaji and Adewumi John Babafemi and Gideon Pieter Adriaan Greeff van Zijl",
title = "Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete: A Review of Advances in Laboratory and Real-Scale Construction Projects",
doi = "10.1016/j.mtsust.2025.101131",
year = "2025",
journal = "Materials Today Sustainability",
pages = "101131",
}
Formatted Citation
M. B. Jaji, A. J. Babafemi and G. P. A. G. van Zijl, “Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete: A Review of Advances in Laboratory and Real-Scale Construction Projects”, Materials Today Sustainability, p. 101131, 2025, doi: 10.1016/j.mtsust.2025.101131.
Jaji, Mustapha Bamidele, Adewumi John Babafemi, and Gideon Pieter Adriaan Greeff van Zijl. “Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete: A Review of Advances in Laboratory and Real-Scale Construction Projects”. Materials Today Sustainability, 2025, 101131. https://doi.org/10.1016/j.mtsust.2025.101131.