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Advancing 3D Printable Concrete with Nanoclays (2025-08)

Rheological and Mechanical Insights for Construction Applications

10.3390/jcs9080449

Si Wen, Carr Liam,  Zia Asad,  Khan Mehran,  McNally Ciaran
Journal Article - Journal of Composites Science, Vol. 9, Iss. 8, No. 449

Abstract

Three-dimensional concrete printing (3DCP) is an emerging technology that improves design flexibility and material efficiency in construction. However, widespread adoption of 3DCP requires overcoming key material challenges. These include controlling rheology for pumpability and buildability and achieving sufficient mechanical strength. This paper provides a comprehensive review of the application of nanoclays (NCs) as a key admixture to address these challenges. The effects of three primary NCs (attapulgite (ATT), bentonite (BEN), and sepiolite (SEP)) on the fresh- and hardened-state properties of printable mortars are systematically analyzed. This review summarize findings on how NCs enhanced thixotropy, yield stress, and cohesion, which are critical for shape retention and the successful printing of multilayered structures. Quantitative analysis reveals that optimized dosages of NCs can increase compressive strength by up to 34% and flexural strength by up to 20%. For enhancing rheology and printability, a dosage of approximately 0.5% by binder weight is often suggested for ATT and SEP. In contrast, BEN can be used at higher replacement levels (up to 20%) to also function as a supplementary cementitious material (SCM), though this significantly impacts workability. This review consolidates the current knowledge to provide a clear framework for selecting appropriate NCs and dosages to develop high-performance, reliable, and sustainable materials for 3DCP applications.

48 References

  1. Abdalqader Ahmed, Sonebi Mohammed, Dedenis Marie, Amziane Sofiane et al. (2022-06)
    Mechanical Performance of 3D Printed Concrete Containing Fly-Ash, Metakaolin and Nano-Clay
  2. Ambily Parukutty, Kaliyavaradhan Senthil, Rajendran Neeraja (2023-05)
    Top Challenges to Widespread 3D Concrete Printing Adoption:
    A Review
  3. Aydin Eylül, Kara Burhan, Bundur Zeynep, Özyurt Nilüfer et al. (2022-08)
    A Comparative Evaluation of Sepiolite and Nano-Montmorillonite on the Rheology of Cementitious Materials for 3D Printing
  4. Bohuchval Marie, Sonebi Mohammed, Amziane Sofiane, Perrot Arnaud (2020-12)
    Effect of Metakaolin and Natural Fibers on Three-Dimensional Printing Mortar
  5. Chen Yu, He Shan, Zhang Yu, Wan Zhi et al. (2021-08)
    3D Printing of Calcined-Clay-Limestone-Based Cementitious Materials
  6. Chen Mingxu, Liu Bo, Li Laibo, Cao Lidong et al. (2020-01)
    Rheological Parameters, Thixotropy and Creep of 3D Printed Calcium-Sulfoaluminate-Cement Composites Modified by Bentonite
  7. Chen Mingxu, Yang Lei, Zheng Yan, Huang Yongbo et al. (2020-04)
    Yield-Stress and Thixotropy-Control of 3D Printed Calcium-Sulfoaluminate Cement Composites with Metakaolin Related to Structural Build-Up
  8. Chougan Mehdi, Ghaffar Seyed, Sikora Paweł, Chung Sang-Yeop et al. (2021-02)
    Investigation of Additive Incorporation on Rheological, Microstructural and Mechanical Properties of 3D Printable Alkali-Activated Materials
  9. Dai Xiaodi, Tao Yaxin, Tittelboom Kim, Schutter Geert (2023-02)
    Rheological and Mechanical Properties of 3D Printable Alkali-Activated Slag Mixtures with Addition of Nano Clay
  10. Gou Hongxiang, Sofi Massoud, Zhang Zipeng, Zhu Mintao et al. (2024-03)
    Combined Printable and Mechanical Analysis of 3D Printed Green High-Strength, Lightweight Engineered Cementitious Composites
  11. Hanratty Niall, Khan Mehran, McNally Ciaran (2024-07)
    The Role of Different Clay Types in Achieving Low-Carbon 3D Printed Concretes
  12. Hopkins Ben, Si Wen, Khan Mehran, McNally Ciaran (2025-06)
    Recent Advancements in Polypropylene Fiber-Reinforced 3D-Printed Concrete:
    Insights into Mix Ratios, Testing Procedures, and Material Behaviour
  13. Kamakshi Tippabhotla, Subramaniam Kolluru (2024-05)
    Rheology-Control and 3D Concrete Printing with Fly Ash-Based Aqueous Nano-Silica Enhanced Alkali-Activated Binders
  14. Kanagasuntharam Sasitharan, Ramakrishnan Sayanthan, Sanjayan Jay (2024-06)
    Encapsulation of Sodium-Silicate to Attain on Demand Buildability Enhancement in Concrete 3D Printing
  15. Kaushik Sandipan, Sonebi Mohammed, Amato Giuseppina, Perrot Arnaud et al. (2022-02)
    Influence of Nano-Clay on the Fresh and Rheological Behavior of 3D Printing Mortar
  16. Kazemian Ali, Yuan Xiao, Meier Ryan, Khoshnevis Behrokh (2019-02)
    Performance-Based Testing of Portland Cement Concrete for Construction-Scale 3D Printing
  17. Khan Mehran, McNally Ciaran (2024-05)
    Recent Developments on Low-Carbon 3D Printing Concrete:
    Revolutionizing Construction Through Innovative Technology
  18. Kilic Ugur, Ma Ji, Baharlou Ehsan, Ozbulut Osman (2023-03)
    Effects of Viscosity-Modifying Admixture and Nano-Clay on Fresh and Rheo-Viscoelastic Properties and Printability Characteristics of Cementitious Composites
  19. Lee Jin, Kim Jae (2022-06)
    Matric-Suction and Its Effect on the Shape Stability of 3D Printed Concrete
  20. Li Haodao, Wei Jingjie, Khayat Kamal (2024-06)
    3D Printing of Fiber-Reinforced Calcined Clay-Limestone-Based Cementitious Materials:
    From Mixture Design to Printability Evaluation
  21. Ma Siwei, Kawashima Shiho (2018-09)
    Rheological and Water Transport Properties of Cement-Pastes Modified with Diutan Gum and Attapulgite-Palygorskite-Nano-Clay for 3D Concrete Printing
  22. Makul Natt (2025-06)
    3D Concrete Printing
  23. Marchon Delphine, Kawashima Shiho, Bessaies-Bey Hela, Mantellato Sara et al. (2018-05)
    Hydration- and Rheology-Control of Concrete for Digital Fabrication:
    Potential Admixtures and Cement-Chemistry
  24. Moeini Mohammad, Hosseinpoor Masoud, Yahia Ammar (2020-05)
    Effectiveness of the Rheometric Methods to Evaluate the Build-Up of Cementitious Mortars Used for 3D Printing
  25. Moeini Mohammad, Hosseinpoor Masoud, Yahia Ammar (2022-04)
    3D Printing of Cement-Based Materials with Adapted Buildability
  26. Natanzi Atteyeh, McNally Ciaran (2020-07)
    Characterising Concrete Mixes for 3D Printing
  27. Nematollahi Behzad, Xia Ming, Sanjayan Jay (2017-07)
    Current Progress of 3D Concrete Printing Technologies
  28. Nikravan Ata, Aydin Tolga, Özyurt Nilüfer, Bundur Zeynep (2024-09)
    Enhancing the Performance of 3D Printed Fiber-Reinforced Mortar:
    Synergistic Effects of Clays and Bacterial Cells as Viscosity-Modifying-Agents
  29. Panda Biranchi, Ruan Shaoqin, Unluer Cise, Tan Ming (2018-11)
    Improving the 3D Printability of High-Volume Fly-Ash Mixtures via the Use of Nano-Attapulgite-Clay
  30. Qian Ye, Kawashima Shiho (2016-09)
    Use of Creep Recovery Protocol to Measure Static Yield-Stress and Structural Rebuilding of Fresh Cement-Pastes
  31. Qian Ye, Schutter Geert (2018-06)
    Enhancing Thixotropy of Fresh Cement-Pastes with Nano-Clay in Presence of Polycarboxylate-Ether Superplasticizer (PCE)
  32. Ramakrishnan Sayanthan, Muthukrishnan Shravan, Sanjayan Jay, Pasupathy Kirubajiny (2021-08)
    Concrete 3D Printing of Lightweight Elements Using Hollow-Core Extrusion of Filaments
  33. Rehman Atta, Kim Jung-Hoon (2021-07)
    3D Concrete Printing:
    A Systematic Review of Rheology, Mix Designs, Mechanical, Microstructural, and Durability Characteristics
  34. Robayo-Salazar Rafael, Muñoz Miguel, Vargas Armando, Gutiérrez Ruby (2024-08)
    Effects of Incorporating Bentonite, Metakaolin, Microsilica, and Calcium-Carbonate on the Rheological Properties of Portland-Cement-Based 3D Printing Inks
  35. Schutter Geert, Lesage Karel, Mechtcherine Viktor, Nerella Venkatesh et al. (2018-08)
    Vision of 3D Printing with Concrete:
    Technical, Economic and Environmental Potentials
  36. Shahmirzadi Mohsen, Gholampour Aliakbar, Kashani Alireza, Ngo Tuan (2023-10)
    Geopolymer Mortars for Use in Construction 3D Printing:
    Effect of LSS, Graphene-Oxide and Nano-Clay at Different Environmental Conditions
  37. Si Wen, Khan Mehran, McNally Ciaran (2025-06)
    A Comprehensive Review of Rheological Dynamics and Process Parameters in 3D Concrete Printing
  38. Sikora Paweł, Chougan Mehdi, Cuevas Villalobos Karla, Liebscher Marco et al. (2021-02)
    The Effects of Nano- and Micro-Sized Additives on 3D Printable Cementitious and Alkali-Activated Composites:
    A Review
  39. Sonebi Mohammed, Dedenis Marie, Abdalqader Ahmed, Perrot Arnaud (2021-11)
    Effect of Red Mud, Nano-Clay, and Natural Fiber on Fresh and Rheological Properties of Three-Dimensional Concrete Printing
  40. Song Hongwei, Li Xinle (2021-05)
    An Overview on the Rheology, Mechanical Properties, Durability, 3D Printing, and Microstructural Performance of Nanomaterials in Cementitious Composites
  41. Tamimi Adil, Alqamish Habib, Khaldoune Ahlam, Alhaidary Haidar et al. (2023-03)
    Framework of 3D Concrete Printing Potential and Challenges
  42. Varela Hugo, Barluenga Gonzalo, Perrot Arnaud (2023-07)
    Extrusion and Structural Build-Up of 3D Printing Cement-Pastes with Fly-Ash, Nano-Clay and VMAs
  43. Varela Hugo, Barluenga Gonzalo, Sonebi Mohammed (2024-09)
    Evaluation of Basalt-Fibers and Nano-Clays to Enhance Extrudability and Buildability of 3D Printing Mortars
  44. Xu Nuoyan, Qian Ye (2023-04)
    Effects of Fiber-Volume Fraction, Fiber Length, Water-Binder Ratio, and Nano-Clay Addition on the 3D Printability of Strain-Hardening Cementitious Composites
  45. Yao Hao, Xie Zonglin, Li Zemin, Huang Chuhan et al. (2021-11)
    The Relationship Between the Rheological Behavior and Inter-Layer Bonding Properties of 3D Printing Cementitious Materials with the Addition of Attapulgite
  46. Zhang Chao, Nerella Venkatesh, Krishna Anurag, Wang Shen et al. (2021-06)
    Mix-Design Concepts for 3D Printable Concrete:
    A Review
  47. Zhang Jingchuan, Wang Jialiang, Dong Sufen, Yu Xun et al. (2019-07)
    A Review of the Current Progress and Application of 3D Printed Concrete
  48. Zhao Zhihui, Chen Mingxu, Zhong Xu, Huang Yongbo et al. (2021-07)
    Effects of Bentonite, Diatomite and Metakaolin on the Rheological Behavior of 3D Printed Magnesium-Potassium-Phosphate-Cement Composites

4 Citations

  1. Kaushik Sandipan, Sonebi Mohammed, Amato Giuseppina, Perrot Arnaud (2026-01)
    Effect of Fly Ash, Basalt Fiber and Attapulgite Nanoclay on the Fresh Properties, Rheology and Shrinkage Behaviour of Printable Concrete
  2. Si Wen, Khan Mehran, McNally Ciaran (2025-11)
    Rheological Optimization and Mechanical Performance Assessment of High-Volume GGBS-Silica Fume Mortars for 3D Printing
  3. Bradshaw James, Balasubramanian Swathi, Si Wen, Khan Mehran et al. (2025-10)
    Towards Greener 3D Printing:
    A Performance Evaluation of Silica Fume-Modified Low-Carbon Concrete
  4. Si Wen, Hopkins Ben, Khan Mehran, McNally Ciaran (2025-09)
    Towards Sustainable Mortar:
    Optimising Sika-Fiber Dosage in Ground Granulated Blast Furnace Slag and Silica Fume Blends for 3D Concrete Printing

BibTeX
@article{si_carr_zia_khan.2025.A3PCwN,
  author            = "Wen Si and Liam Carr and Asad Zia and Mehran Khan and Ciaran McNally",
  title             = "Advancing 3D Printable Concrete with Nanoclays: Rheological and Mechanical Insights for Construction Applications",
  doi               = "10.3390/jcs9080449",
  year              = "2025",
  journal           = "Journal of Composites Science",
  volume            = "9",
  number            = "8",
  pages             = "449",
}
Formatted Citation

W. Si, L. Carr, A. Zia, M. Khan and C. McNally, “Advancing 3D Printable Concrete with Nanoclays: Rheological and Mechanical Insights for Construction Applications”, Journal of Composites Science, vol. 9, no. 8, p. 449, 2025, doi: 10.3390/jcs9080449.

Si, Wen, Liam Carr, Asad Zia, Mehran Khan, and Ciaran McNally. “Advancing 3D Printable Concrete with Nanoclays: Rheological and Mechanical Insights for Construction Applications”. Journal of Composites Science 9, no. 8 (2025): 449. https://doi.org/10.3390/jcs9080449.