Rheological Optimization of 3D-Printed Cementitious Materials Using Response Surface Methodology (2025-08)¶

This study employed response surface methodology (RSM) to optimize admixture proportions in 3D-printed cementitious materials, with the aim of enhancing printability. Based on preliminary tests, three additives, namely, an accelerator, hydroxypropyl methylcellulose (HPMC), and polycarboxylate superplasticizer (PCE), were incorporated to evaluate their effects on flowability and dynamic yield stress. A Box–Behnken central composite design was used to establish a mathematical model, followed by the RSM-driven optimization of mix proportions. The optimized formulation (0.32% accelerator, 0.24% HPMC, and 0.23% PCE) achieved a flowability of 147.5 mm and a dynamic yield stress of 711 Pa, which closely matched the predicted values and fulfilled the printability requirements, thus establishing RSM as an effective approach for designing printable cementitious composites. This approach established an RSM-based optimization framework for mix proportion design. These findings offer a mechanistic framework for rational 3DPC mixture design, combining theoretical insights and practical implementation in additive construction.