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Optimizing 3D Geopolymer Concrete for Sustainable Construction (2025-04)

A Review of Material Selection, Printing Methods, and Properties

10.1007/s41062-025-01970-7

 Maralapalle Vedprakash,  Kumavat Hemraj, Nadaf Maheboobsab, Zende Aijaz, Mishra S.,  Iyer Rajiv
Journal Article - Innovative Infrastructure Solutions, Vol. 10, Iss. 5

Abstract

This review examined advancements in extrusion-based 3D printed geopolymers, focusing on how material choices and printing methods affected their properties. It is also analyzed the link between fresh mix properties, workability, printing, and shape retention. Generally, by increasing Ground Granulated Blast-Furnace Slag content improves both compressive and flexural strength in both cast and printed specimens. Glass fibers negatively affected compressive strength due to fiber orientation during printing. Replaced Lime Stone with Ordinary Portland Cement improved compressive strength but decreased flexural strength due to weaker bonding. The review also explores the economic and environmental benefits of 3D geopolymer concrete (3D GPC). However, geopolymer activators can be expensive and the embodied energy of the mix heavily depends on the activator type. The review also highlighted the potential of 3D geopolymer concrete for sustainable construction. Meticulous selection of materials, optimized printing, and economic considerations are essential for making 3D GPC a more viable and eco-friendly construction technology.

76 References

  1. Albar Abdulrahman, Chougan Mehdi, Kheetan Mazen, Swash Mohammad et al. (2020-04)
    Effective Extrusion-Based 3D Printing System Design for Cementitious-Based Materials
  2. Alghamdi Hussam, Nair Sooraj, Neithalath Narayanan (2019-02)
    Insights into Material-Design, Extrusion Rheology, and Properties of 3D Printable Alkali-Activated Fly-Ash-Based Binders
  3. Al-Qutaifi Sarah, Nazari Ali, Bagheri Ali (2018-07)
    Mechanical Properties of Layered Geopolymer Structures Applicable in Concrete 3D Printing
  4. Bai Gang, Wang Li, Ma Guowei, Sanjayan Jay et al. (2021-03)
    3D Printing Eco-Friendly Concrete Containing Under-Utilised and Waste Solids as Aggregates
  5. Batikha Mustafa, Jotangia Rahul, Baaj Mohamad, Mousleh Ibrahim (2021-12)
    3D Concrete Printing for Sustainable and Economical Construction:
    A Comparative Study
  6. Bong Shin, Nematollahi Behzad, Nazari Ali, Xia Ming et al. (2018-09)
    Fresh and Hardened Properties of 3D Printable Geopolymer Cured in Ambient Temperature
  7. Bong Shin, Nematollahi Behzad, Xia Ming, Ghaffar Seyed et al. (2022-04)
    Properties of Additively Manufactured Geopolymer Incorporating Mineral-Wollastonite-Micro-Fibers
  8. Bong Shin, Nematollahi Behzad, Xia Ming, Nazari Ali et al. (2019-09)
    Properties of 3D Printable Ductile Fiber-Reinforced Geopolymer Composite for Digital Construction Applications
  9. Bong Shin, Xia Ming, Nematollahi Behzad, Shi Caijun (2021-04)
    Ambient Temperature Cured ‘Just-Add-Water’ Geopolymer for 3D Concrete Printing Applications
  10. Cheikh Khadija, Rémond Sébastien, Khalil Noura, Aouad Georges (2017-04)
    Numerical and Experimental Studies of Aggregate-Blocking in Mortar-Extrusion
  11. Chen Yu, Figueiredo Stefan, Yalçınkaya Çağlar, Çopuroğlu Oğuzhan et al. (2019-04)
    The Effect of Viscosity-Modifying Admixture on the Extrudability of Limestone and Calcined-Clay-Based Cementitious Material for Extrusion-Based 3D Concrete Printing
  12. Chen Yidong, Zhang Yunsheng, Pang Bo, Liu Zhiyong et al. (2021-05)
    Extrusion-Based 3D Printing Concrete with Coarse Aggregate:
    Printability and Direction-Dependent Mechanical Performance
  13. Chougan Mehdi, Ghaffar Seyed, Jahanzat Mohammad, Albar Abdulrahman et al. (2020-04)
    The Influence of Nano-Additives in Strengthening Mechanical Performance of 3D Printed Multi-Binder Geopolymer Composites
  14. Christen Heidi, Zijl Gideon, Villiers Wibke (2022-05)
    The Incorporation of Recycled Brick-Aggregate in 3D Printed Concrete
  15. Dey Dhrutiman, Srinivas Dodda, Panda Biranchi, Suraneni Prannoy et al. (2022-02)
    Use of Industrial Waste-Materials for 3D Printing of Sustainable Concrete:
    A Review
  16. Ding Tao, Xiao Jianzhuang, Zou Shuai, Wang Yu (2020-06)
    Hardened Properties of Layered 3D Printed Concrete with Recycled Sand
  17. Ding Tao, Xiao Jianzhuang, Zou Shuai, Yu Jiangtao (2021-03)
    Flexural Properties of 3D Printed Fiber-Reinforced Concrete with Recycled Sand
  18. Giridhar Greeshma, Prem Prabhat, Kumar Shankar (2023-01)
    Development of Concrete Mixes for 3D Printing Using Simple Tools and Techniques
  19. Gosselin Clément, Duballet Romain, Roux Philippe, Gaudillière-Jami Nadja et al. (2016-03)
    Large-Scale 3D Printing of Ultra-High-Performance Concrete:
    A New Processing Route for Architects and Builders
  20. Guo Xiaolu, Yang Junyi, Xiong Guiyan (2020-09)
    Influence of Supplementary Cementitious Materials on Rheological Properties of 3D Printed Fly-Ash-Based Geopolymer
  21. Hambach Manuel, Volkmer Dirk (2017-02)
    Properties of 3D Printed Fiber-Reinforced Portland-Cement-Paste
  22. Han Yilong, Yang Zhihan, Ding Tao, Xiao Jianzhuang (2020-08)
    Environmental and Economic Assessment on 3D Printed Buildings with Recycled Concrete
  23. Jeon Kwang-Hyun, Park Min-Beom, Kang Min-Kyung, Kim Jung-Hoon (2013-11)
    Development of an Automated Freeform Construction System and Its Construction Materials
  24. Ji Guangchao, Ding Tao, Xiao Jianzhuang, Du Shupeng et al. (2019-05)
    A 3D Printed Ready-Mixed Concrete Power-Distribution Substation:
    Materials and Construction Technology
  25. Jo Jun, Jo Byung, Cho Woohyun, Kim Jung-Hoon (2020-03)
    Development of a 3D Printer for Concrete Structures:
    Laboratory Testing of Cementitious Materials
  26. Kazemian Ali, Yuan Xiao, Cochran Evan, Khoshnevis Behrokh (2017-04)
    Cementitious Materials for Construction-Scale 3D Printing:
    Laboratory Testing of Fresh Printing Mixture
  27. Khan Mohd (2020-04)
    Mix Suitable for Concrete 3D Printing:
    A Review
  28. Labonnote Nathalie, Rønnquist Anders, Manum Bendik, Rüther Petra (2016-09)
    Additive Construction:
    State of the Art, Challenges and Opportunities
  29. Le Thanh, Austin Simon, Lim Sungwoo, Buswell Richard et al. (2012-01)
    Mix-Design and Fresh Properties for High-Performance Printing Concrete
  30. Li Zhijian, Wang Li, Ma Guowei (2020-01)
    Mechanical Improvement of Continuous Steel-Micro-Cable-Reinforced Geopolymer Composites for 3D Printing Subjected to Different Loading Conditions
  31. Lim Jian, Panda Biranchi, Pham Quang-Cuong (2018-05)
    Improving Flexural Characteristics of 3D Printed Geopolymer Composites with In-Process Steel-Cable-Reinforcement
  32. Liu Siyu, Lu Bing, Li Hongliang, Pan Zehua et al. (2022-03)
    A Comparative Study on Environmental Performance of 3D Printing and Conventional Casting of Concrete Products with Industrial Wastes
  33. Ma Guowei, Li Zhijian, Wang Li, Bai Gang (2018-10)
    Micro-Cable-Reinforced Geopolymer Composite for Extrusion-Based 3D Printing
  34. Manikandan Karthick, Wi Kwangwoo, Zhang Xiao, Wang Kejin et al. (2020-03)
    Characterizing Cement Mixtures for Concrete 3D Printing
  35. Mechtcherine Viktor, Nerella Venkatesh, Will Frank, Näther Mathias et al. (2019-08)
    Large-Scale Digital Concrete Construction:
    CONPrint3D Concept for On-Site, Monolithic 3D Printing
  36. Moeini Mohammad, Hosseinpoor Masoud, Yahia Ammar (2020-05)
    Effectiveness of the Rheometric Methods to Evaluate the Build-Up of Cementitious Mortars Used for 3D Printing
  37. Mohammad Malek, Masad Eyad, Ghamdi Sami (2020-12)
    3D Concrete Printing Sustainability:
    A Comparative Life Cycle Assessment of Four Construction Method Scenarios
  38. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2020-09)
    Effect of Microwave-Heating on Inter-Layer Bonding and Buildability of Geopolymer 3D Concrete Printing
  39. Nematollahi Behzad, Xia Ming, Bong Shin, Sanjayan Jay (2018-09)
    Hardened Properties of 3D Printable One-Part Geopolymer for Construction Applications
  40. Nerella Venkatesh, Hempel Simone, Mechtcherine Viktor (2019-02)
    Effects of Layer-Interface Properties on Mechanical Performance of Concrete Elements Produced by Extrusion-Based 3D Printing
  41. Nerella Venkatesh, Mechtcherine Viktor (2019-02)
    Studying the Printability of Fresh Concrete for Formwork-Free Concrete Onsite 3D Printing Technology (CONPrint3D)
  42. Noaimat Yazeed, Ghaffar Seyed, Chougan Mehdi, Kheetan Mazen (2022-12)
    A Review of 3D Printing Low-Carbon Concrete with One-Part Geopolymer:
    Engineering, Environmental and Economic Feasibility
  43. Oosthuizen Jandré, Babafemi Adewumi, Walls Richard (2023-10)
    3D Printed Recycled Plastic Eco-Aggregate (Resin8) Concrete
  44. Panda Biranchi, Bhagath Singh Gangapatnam, Unluer Cise, Tan Ming (2019-02)
    Synthesis and Characterization of One-Part Geopolymers for Extrusion-Based 3D Concrete Printing
  45. Panda Biranchi, Mohamed Nisar, Tay Yi, Tan Ming (2018-09)
    Bond Strength in 3D Printed Geopolymer Mortar
  46. Panda Biranchi, Paul Suvash, Lim Jian, Tay Yi et al. (2017-08)
    Additive Manufacturing of Geopolymer for Sustainable Built Environment
  47. Panda Biranchi, Paul Suvash, Mohamed Nisar, Tay Yi et al. (2017-09)
    Measurement of Tensile Bond Strength of 3D Printed Geopolymer Mortar
  48. Panda Biranchi, Ruan Shaoqin, Unluer Cise, Tan Ming (2020-01)
    Investigation of the Properties of Alkali-Activated Slag Mixes Involving the Use of Nano-Clay and Nucleation-Seeds for 3D Printing
  49. Panda Biranchi, Tan Ming (2018-03)
    Experimental Study on Mix Proportion and Fresh Properties of Fly-Ash-Based Geopolymer for 3D Concrete Printing
  50. Panda Biranchi, Tan Ming (2018-11)
    Rheological Behavior of High-Volume Fly-Ash Mixtures Containing Micro-Silica for Digital Construction Application
  51. Panda Biranchi, Unluer Cise, Tan Ming (2018-10)
    Investigation of the Rheology and Strength of Geopolymer Mixtures for Extrusion-Based 3D Printing
  52. Panda Biranchi, Unluer Cise, Tan Ming (2019-08)
    Extrusion and Rheology Characterization of Geopolymer Nanocomposites Used in 3D Printing
  53. Papachristoforou Michail, Mitsopoulos Vasilios, Stefanidou Maria (2018-10)
    Evaluation of Workability Parameters in 3D Printing Concrete
  54. Paul Suvash, Tay Yi, Panda Biranchi, Tan Ming (2017-08)
    Fresh and Hardened Properties of 3D Printable Cementitious Materials for Building and Construction
  55. Perrot Arnaud, Rangeard Damien, Pierre Alexandre (2015-02)
    Structural Build-Up of Cement-Based Materials Used for 3D Printing-Extrusion-Techniques
  56. Rahul Attupurathu, Santhanam Manu (2020-02)
    Evaluating the Printability of Concretes Containing Lightweight Coarse Aggregates
  57. Rahul Attupurathu, Santhanam Manu, Meena Hitesh, Ghani Zimam (2018-12)
    3D Printable Concrete:
    Mixture-Design and Test-Methods
  58. Rahul Attupurathu, Santhanam Manu, Meena Hitesh, Ghani Zimam (2019-08)
    Mechanical Characterization of 3D Printable Concrete
  59. Schröfl Christof, Nerella Venkatesh, Mechtcherine Viktor (2018-09)
    Capillary Water Intake by 3D Printed Concrete Visualised and Quantified by Neutron Radiography
  60. Suntharalingam Thadshajini, Nagaratnam Brabha, Poologanathan Keerthan, Hackney Phil et al. (2019-12)
    Effect of Polypropylene-Fibers on the Workability Parameters of Extrudable Cementitious Materials
  61. Tay Yi, Li Mingyang, Tan Ming (2019-04)
    Effect of Printing Parameters in 3D Concrete Printing:
    Printing Region and Support Structures
  62. Ting Guan, Tay Yi, Tan Ming (2021-04)
    Experimental Measurement on the Effects of Recycled Glass-Cullets as Aggregates for Construction 3D Printing
  63. Weng Yiwei, Li Mingyang, Ruan Shaoqin, Wong Teck et al. (2020-03)
    Comparative Economic, Environmental and Productivity-Assessment of a Concrete Bathroom Unit Fabricated Through 3D Printing and a Pre-Cast Approach
  64. Weng Yiwei, Li Mingyang, Tan Ming, Qian Shunzhi (2018-01)
    Design 3D Printing Cementitious Materials via Fuller-Thompson-Theory and Marson-Percy-Model
  65. Wu Yiwen, Liu Chao, Liu Huawei, Zhang Zhenzi et al. (2021-07)
    Study on the Rheology and Buildability of 3D Printed Concrete with Recycled Coarse Aggregates
  66. Xiao Jianzhuang, Han Nv, Zhang Lihai, Zou Shuai (2021-05)
    Mechanical and Microstructural Evolution of 3D Printed Concrete with Polyethylene-Fiber and Recycled Sand at Elevated Temperatures
  67. Xiao Jianzhuang, Zou Shuai, Ding Tao, Duan Zhenhua et al. (2021-08)
    Fiber-Reinforced Mortar with 100% Recycled Fine Aggregates:
    A Cleaner Perspective on 3D Printing
  68. Xiao Jianzhuang, Zou Shuai, Yu Ying, Wang Yu et al. (2020-09)
    3D Recycled Mortar Printing:
    System-Development, Process-Design, Material-Properties and On-Site-Printing
  69. Yang Hongxiong, Chung Jacky, Chen Yuhong, Li Yijia (2018-06)
    The Cost Calculation Method of Construction 3D Printing Aligned with Internet of Things
  70. Yuan Qiang, Gao Chao, Huang Tingjie, Zuo Shenghao et al. (2022-03)
    Factors Influencing the Properties of Extrusion-Based 3D Printed Alkali-Activated Fly-Ash-Slag Mortar
  71. Zhang Chao, Nerella Venkatesh, Krishna Anurag, Wang Shen et al. (2021-06)
    Mix-Design Concepts for 3D Printable Concrete:
    A Review
  72. Zhang Hanghua, Xiao Jianzhuang (2021-08)
    Plastic Shrinkage and Cracking of 3D Printed Mortar with Recycled Sand
  73. Zhang Yu, Zhang Yunsheng, Liu Guojian, Yang Yonggan et al. (2018-04)
    Fresh Properties of a Novel 3D Printing Concrete Ink
  74. Zhang Yu, Zhang Yunsheng, She Wei, Yang Lin et al. (2019-01)
    Rheological and Hardened Properties of the High-Thixotropy 3D Printing Concrete
  75. Zhong Hui, Zhang Mingzhong (2022-02)
    3D Printing Geopolymers:
    A Review
  76. Zhu Binrong, Pan Jinlong, Nematollahi Behzad, Zhou Zhenxin et al. (2019-07)
    Development of 3D Printable Engineered Cementitious Composites with Ultra-High Tensile Ductility for Digital Construction

0 Citations

BibTeX
@article{mara_kuma_nada_zend.2025.O3GCfSC,
  author            = "Vedprakash Maralapalle and Hemraj R. Kumavat and Maheboobsab B. Nadaf and Aijaz Ahmad Zende and S. Sangita Mishra and Rajiv Iyer",
  title             = "Optimizing 3D Geopolymer Concrete for Sustainable Construction: A Review of Material Selection, Printing Methods, and Properties",
  doi               = "10.1007/s41062-025-01970-7",
  year              = "2025",
  journal           = "Innovative Infrastructure Solutions",
  volume            = "10",
  number            = "5",
}
Formatted Citation

V. Maralapalle, H. R. Kumavat, M. B. Nadaf, A. A. Zende, S. S. Mishra and R. Iyer, “Optimizing 3D Geopolymer Concrete for Sustainable Construction: A Review of Material Selection, Printing Methods, and Properties”, Innovative Infrastructure Solutions, vol. 10, no. 5, 2025, doi: 10.1007/s41062-025-01970-7.

Maralapalle, Vedprakash, Hemraj R. Kumavat, Maheboobsab B. Nadaf, Aijaz Ahmad Zende, S. Sangita Mishra, and Rajiv Iyer. “Optimizing 3D Geopolymer Concrete for Sustainable Construction: A Review of Material Selection, Printing Methods, and Properties”. Innovative Infrastructure Solutions 10, no. 5 (2025). https://doi.org/10.1007/s41062-025-01970-7.